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Publications

2022

235. Metal-metal-to-ligand Charge Transfer in Pt(II) Dimers Bridged by Pyridyl and Quinoline Thiols. Roy, S.; Lopez, A.A.; Yarnell, J.E.; Castellano, F.N. Inorg. Chem. 202261, 121-130. https://doi.org/10.1021/acs.inorgchem.1c02469

234. A biohybrid strategy for enabling photoredox catalysis with low-energy light. Cesana, P.T.; Li, B.X.; Shepard, S.G.; Ting, S.I.; Hart, S.M.; Olson, C.M.; Martinez-Alvarado, J.I.; Son, M.; Castellano, F.N.; Doyle, A.G.; MacMillan, D.W.C.; Schlau-Cohen, G.S. Chem 2022, 8, 174-185. https://doi.org/10.1016/j.chempr.2021.10.010

2021

233. Photochemical H2 Evolution from Bis(diphosphine)nickel Hydrides Enables Low-Overpotential Electrocatalysis. Stratakes, B.M.; Wells, K.A.; Kurtz, D.A.; Castellano, F.N.; Miller, A.J.M. J. Am. Chem. Soc. 2021143, 21388-21401. https://doi.org/10.1021/jacs.1c10628

232. CsPbI3 Nanocrystals Go with the Flow: From Formation Mechanism to Continuous Nanomanufacturing. Antami, K.; Bateni, F.; Ramezani, M.; Hauke, C.E.; Castellano, F.N.; Abolhasani, M. Adv. Funct. Mater. 2021, 2108687.  https://doi.org/10.1002/adfm.202108687

231. General Design Rules for Bimetallic Platinum(II) Complexes. Mills, A.; Valentine, A.; Hoang, K.; Roy, S.; Castellano, F.N.; Chen, L.X.; Li, X. J. Phys. Chem. A 2021125, 9438-9449. https://doi.org/10.1021/acs.jpca.1c05044

230. Excited-state Bond Contraction and Charge Migration in a Platinum Dimer Complex Characterized by X-Ray and Optical Transient Absorption Spectroscopy. Weingartz, N.P.; Mara, M.W.; Roy, S.; Hong, J.; Chakraborty, A.; Brown-Xu, S.E.; Phelan, B.T.; Castellano, F.N.; Chen, L.X. J. Phys. Chem. A 2021125, 8891-8898. https://pubs.acs.org/doi/10.1021/acs.jpca.1c07201

229. Understanding the Influence of Geometric and Electronic Structure on the Excited State Dynamical and Photoredox Properties of Perinone Chromophores. Wells, K.A.; Palmer, J.R.; Yarnell, J.E.; Garakyaraghi, S.; Pemberton, B.C.; Favale, J.M.; Valchar, M.K.; Chakraborty, A.; Castellano, F.N.; Phys. Chem. Chem. Phys. 2021, 23, 24200–24210. https://doi.org/10.1039/D1CP03870B

228. High Efficiency Deep Red to Yellow Photochemical Upconversion under Solar Irradiance. Gallaher, J.K.; Wright, K.M.; Frazer, N.L.; MacQueen, R.W.; Crossley, M.J.; Castellano, F.N.; Schmidt, T.W. Energy Environ. Sci. 2021,14, 5541-5551. https://doi.org/10.1039/D1EE02197D 

227. Accessing the Triplet Manifold of Naphthalenebenzimidazole-phenanthroline in Rhenium(I) Bichromophores. Wells, K.A.; Yarnell, J.E.; Sheykhi, S.; Palmer, J.R.; Yonemoto, D.T.; Joyce, R.; Garakyaraghi, S.; Castellano, F.N. Dalton Trans. 2021, 50, 13086-13095.https://doi.org/10.1039/D1DT02329B

226. Photodriven Elimination of Chlorine from Germanium and Platinum in a Dinuclear Pt(II) → Ge(IV)Complex. Karimi, M.; Tabei, E.S.; Fayad, R.; Saber, M.R.; Danilov, E.O.; Castellano, F.N.; Gabbai, F.P. Angew. Chem. Int. Ed. 2021, 41, 22526-22532. https://doi.org/10.1002/anie.202107485

225. Passivation of Electron Trap States in InP Quantum Dots with Benzoic Acid Ligands. Zhang, X.; Hudson, M.H.; Castellano, F.N. J. Phys. Chem. C 2021, 125, 18362-18371. https://doi.org/10.1021/acs.jpcc.1c05594

224. Continuous Biphasic Chemical Processes in a Four-phase Segmented Flow Reactor. Volk, A.A.; Epps, R.W.; Yonemoto, D.; Castellano, F.N.; Albohasani, M. React. Chem. Eng. 2021, 6, 1367-1375. https://doi.org/10.1039/D1RE00247C

223. Ultrafast Excited State Dynamics of Photoluminescent Pt(II) Dimers Probed by a Coherent Vibrational Wavepacket. Kim, P.; Valentine, A.J.S.; Roy, S.; Mills, A.W.; Chakraborty, A.; Castellano, F.N.; Li, X.; Chen, L.X. J. Phys. Chem. Lett. 2021, 12, 6794-6803. https://doi.org/10.1021/acs.jpclett.1c01289 

222. Next Generation Cuprous Phenanthroline MLCT Photosensitizer Featuring Cyclohexyl Substituents. Rosko, M.C.; Wells, K.A.; Hauke, C.E.; Castellano, F.N. Inorg. Chem. 2021, 60, 8394-8403. https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c01242

221. Low Power Threshold Photochemical Upconversion using a Zirconium(IV) LMCT Photosensitizer. Yang, M.; Sheykhi, S.; Zhang, Y.; Milsmann, C.; Castellano, F.N. Chem. Sci. 2021, https://doi.org/10.1039/D1SC01662H

220. Ligand-to-Copper Charge Transfer: A General Catalytic Approach to Aromatic Decarboxylative Functionalization. Chen, T.Q.; Pedersen, P.S.; Dow, N.W.; Fayad, R.; Hauke, C.E.; Rosko, M.C.; Danilov, E.O.; Blakemore, D.C.; Dechert-Schmitt, A.-M.; Knauber, T.; Castellano, F.N.; MacMillan, D.W.C. ChemRxiv 2021. https://chemrxiv.org/engage/chemrxiv/article-details/60c757b29abda20e04f8e7b7

219. Controlling Thermally Activated Delayed Photoluminescence in CdSe Quantum Dots through Triplet Acceptor Surface Coverage. Yonemoto, D.T.; Papa, C.M.; Sheykhi, S.; Castellano F.N. J. Phys. Chem. Lett. 2021, 12, 3718-3723. https://pubs.acs.org/doi/10.1021/acs.jpclett.1c00746

218. Shallow Distance-dependent Triplet Energy Migration Mediated by Endothermic Charge-transfer. Lai, R.; Liu, Y.; Luo, X.; Chen, L.; Han, Y.; Lv, M.; Ling, G.; Chen, J.; Zhang, C.; Di, D.; Scholes, G.D.; Castellano, F.N.; Wu, K. Nat. Commun. 2021, 12, 1532. https://doi.org/10.1038/S41467-021-21561-1

2020

217. Vibronic and Excitonic Dynamics in Perylenediimide Dimers and Tetramers. van Stokkum, I.H.M; Jumper, C.C.; Lee, T.S.; Myahkostupov, M.; Castellano, F.N.; Scholes, G.D. J. Chem. Phys. 2020, 153, 224101-1-224101-10. https://doi.org/10.1063/5.0024530

216. Photochemical Upconversion in Water using Cu(I) MLCT Excited States: Role of Energy Shuttling at the Micellar/Water Interface. Fayad, R.; Bui, A.-T.; Shepard, S.G.; Castellano, F.N. ACS Appl. Energy Mater. 2020, 3,12557–12564. https://doi.org/10.1021/acsaem.0c02492

215. Photophysical and Ultrafast Processes in Rhenium(I) Diimine Dicarbonyls. Atallah, H.; Taliaferro, C.M.; Wells, K. A.; Castellano, F.N. Dalton Trans. 2020, 49, 11565-11576. https://doi.org/10.1039/D0DT01765E

214. Visible-Light Initiated Free Radical Polymerization by Homomolecular Triplet-Triplet Annihilation. Awwad, N.; Bui, A.T.; Danilov, E.O.; Castellano, F.N. Chem 2020, 6, 1-15. https://doi.org/10.1016/j.chempr.2020.08.019

213. Ligand-Triplet Migration in Iridium(III) Cyclometalates Featuring 𝜋-Conjugated Isocyanide Ligands. Favale, J.M.; Hauke, C.E.; Danilov, E.O.; Yarnell, J.E.; Castellano, F.N. Dalton Trans. 2020, 49, 9995-10002. https://doi.org/10.1039/D0DT02100H

212. Direct Evidence of Visible-Light Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II). Fayed, R.; Engl, S.; Danilov, E.O.; Hauke, C.; Reiser, O.; Castellano, F.N. J. Phys. Chem. Lett. 2020, 11, 5345-5349. https://dx.doi.org/10.1021/acs.jpclett.0c01601

211. Visible-Light-Driven Triplet Sensitization of Polycyclic Aromatic Hydrocarbons Using Thionated Perinones. Palmer, J.R.; Wells, K.A.; Yarnell, J.E.; Favale, J.M.; Castellano, F.N. J. Phys. Chem. Lett. 2020, 11, 5092-5099. https://doi.org/10.1021/acs.jpclett.0c01634

210. Quantum Yield of Photon Upconversion via Triplet-Triplet Annihilation. Zhou, Y.; Castellano, F.N.; Schmidt, T.W.; Hanson, K. ACS Energy Lett. 2020, 5, 2322-2326. https://dx.doi.org/10.1021/acsenergylett.0c01150

209. Thermally Activated Delayed Photoluminescence: Deterministic Control of Excited State Decay. Papa, C.M.; Yonemoto, D.T.; Mongin, C.; Castellano, F.N. J. Am. Chem. Soc. 2020, 142, 10883-10893. https://doi.org/10.1021/jacs.0c03331

208. Energy Migration Processes in Re(I) MLCT Complexes Featuring a Chromophoric Ancillary Ligand. Wells, K.A.; Yarnell, J.E.; Palmer, J.R.; Lee, T.S.; Papa, C.M.; Castellano, F.N. Inorg. Chem. 2020, 59, 8259-8271.  https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.0c00644

207. Towards Radiation Detection using Cs2AgBiBr6 Double Perovskite Single Crystals. Zhang, Z.; Chung, C.-C.; Huang, Z.; Vetter, E.; Seyitliyev, D.; Sun, D.; Gundogdu, K.; Castellano, F.N.; Danilov, E.O.; Yang, G. Mat. Lett. 2020, 269, 127667. https://doi.org/10.1016/j.matlet.2020.127667

206. TIPS-pentacene triplet exciton generation on PbS quantum dots results from indirect sensitization. Papa, C.M.; Garakyaraghi, S.; Granger, D.B.; Anthony, J.E.; Castellano, F.N. Chem. Sci. 2020, 11, 5690-5696. https://dx.doi.org/10.1039/d0sc00310g

205. 3d-d Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications. Ting, S.; Garakyaraghi, S.; Taliaferro, C.M.; Shields, B.; Scholes, G.D.; Castellano, F.N.; Doyle, A.G. J. Am. Chem. Soc. 2020, 142, 5800-5810. https://dx.doi.org/10.1021/jacs.0c00781

204. Delayed Fluorescence in a Zr(IV) Photosensitizer with Ligand-to-Metal Charge Transfer Excited States. Zhang, Y.; Lee, T.S.; Favale, J.M.; Petersen, J.L.; Scholes, G.D.; Castellano, F.N.; Milsmann, C. Nat. Chem. 2020, 12, 345-352. https://doi.org/10.1038/s41557-020-0430-7

203. A Robust Visible-Light-Harvesting Cyclometalated Ir(III) Diimine Sensitizer for Homogeneous Photocatalytic Hydrogen Production. Yang, M.; Yarnell, J.E.; El Roz, K.; Castellano, F.N. ACS Appl. Energy Mater. 2020, 3, 1842-1853. https://pubs.acs.org/doi/10.1021/acsaem.9b02269

202. Mechanisms of Triplet Energy Transfer Across the Inorganic Nanocrystal/Organic Molecule Interface. Luo, X.; Han, Y.; Chen, Z.; Li, Y.; Liang, G.; Liu, X.; Ding, T.; Nie, C.; Wang, M.; Castellano, F.N.; Wu, K. Nat. Commun. 2020, 11, 28. https://doi.org/10.1038/s41467-019-13951-3

2019

201. Low Temperature Cathodoluminescence Study of Fe doped β-Ga2O3. Hany, I.; Yang, G.; Zhou, C.E.; Sun, C.; Gundogdu, K.; Seyitliyev, D.; Danilov, E.O.; Castellano, F.N.; Murty, K.; Sun, D.; Vetter, E. Mat. Lett. 2019, 257, 126744. https://doi.org/10.1016/j.matlet.2019.126744

200. Resolving the Ultrafast Intersystem Crossing in a Bimetallic Platinum Complex. Valentine, A.J.S.; Radler, J.J.; Castellano, F.N.; Chen, L.X.; Li, X. J. Chem. Phys. 2019, 151, 114303. https://doi.org/10.1063/1.5115169

199. Excited-State Triplet Equilibria in a Series of Re(I)-Naphthalimide Bichromophores. Yarnell, J.E.; Wells, K.A.; Palmer, J.R.; Breaux, J.M.; Castellano, F.N. J. Phys. Chem. B 2019, 123, 7611-7627. (Beratan Festschrift) http://dx.doi.org/10.1021/acs.jpcb.9b05688

198. Photophysical Processes in Re(I) Diimine Tricarbonyl Arylisocyanides Featuring Three Interacting Triplet Excited States. Favale, J.M.; Danilov, E.O.; Yarnell, J.E.; Castellano, F.N. Inorg. Chem. 2019, 58, 8750-8762.   https://doi.org/10.1021/acs.inorgchem.9b01155

197. Degradation Mechanism in Cu(In,Ga)Se2 Materials and Solar Cells Due to Moisture and Heat Treatment of the Absorber Layer. Karki, S.; Paul, P; Rajan, G.; Rockett, A.; Danilov, E.O.; Castellano, F.N. Arehart, A.; Marsillac, S. IEEE J. Photovolt. 2019, 9, 1138-1143. https://ieeexplore.ieee.org/document/8708908

196. Facile Room Temperature Anion Exchange Reactions of Inorganic Perovskite Quantum Dots Enabled by a Modular Microfluidic Platform. Abdel-Latif, K.; Epps, R.W.; Kerr, C.B.; Papa, C.M.; Castellano, F.N.; Abolhasani, M. Adv. Funct. Mater. 2019, 1900712. https://doi.org/10.1002/adfm.201900712

195. Realization of High-efficiency Fluorescent Organic Light-emitting with Low Drive Voltage. Salehi, A.; Dong, C.; Shin, D.-H.; Zhu, L.; Papa, C.; Bui, A.T.; Castellano, F.N.; So, F. Nat. Commun. 2019, 10, 2305. https://doi.org/10.1038/s41467-019-10260-7

194. Analysis of Recombination Mechanisms in RbF treated CIGS solar cells. Karki, S.; Paul, P; Rajan, G.; Rockett, A.; Danilov, E.O.; Castellano, F.N. Arehart, A.; Marsillac, S. IEEE J. Photovolt. 2019, 9, 313-318. https://ieeexplore.ieee.org/document/8521670

2018

193. Excited state switching between ligand-centered and charge transfer modulated by metal-carbon bonds in cyclopentadienyl iridium complexes. Deaton,J.C.; Taliaferro, C.M.; Pitman, C.L.; Czerniewiec,R.; Jakubikova, E.; Miller, A.J.M.; Castellano, F.N. Inorg. Chem. 2018, 57, 15445-15461. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02753

192. Temperature dependence of photophysical properties of a dinuclear C^N-cyclometalated Pt(II) complex with an intimate Pt-Pt contact. Zero-field splitting and sub-state decay rates. Deaton, J.C.; Chakraborty, A.; Czerwieniec, R.; Yersin, H.; Castellano, F.N. Phys. Chem. Chem. Phys. 2018, 20, 25096 – 25104. https://pubs.rsc.org/en/Content/ArticleLanding/2018/CP/C8CP05213A#!divAbstract

191. Bathophenanthroline Disulfonate Ligand-induced Self-assembly of Ir(III) Complexes in Water: An Intriguing Class of Photoluminescent Soft Materials. McGoorty, M.M.; Singh, A.; Deaton, T.A. Peterson, B.; Taliaferro, C.M.; Yingling, Y.G.; Castellano, F.N. ACS Omega 2018, 3, 14027-14038. https://pubs.acs.org/doi/full/10.1021/acsomega.8b02034

190. Long-Lived Triplet Excited State in a Platinum(II) Perylene Monoimide Complex. Yarnell, J.E.; Chakraborty, A.; Myahkostupov, M.; Wright, K.M.; Castellano, F.N. Dalton Trans. 2018, 47, 15071-15081. https://pubs.rsc.org/en/content/articlehtml/2018/dt/c8dt02496k

188. Energy Transfer Dynamics in Triplet-Triplet Annihilation Upconversion Using a Bichromophoric Heavy-Atom-Free Sensitizer. Chen, Q.; Liu, Y.; Guo, X.; Garakyaraghi, S.; Papa, C.M.; Castellano, F.N.; Zhao, D.; Ma, Y. J. Phys. Chem. A 2018, 122,6673-6682. https://pubs.acs.org/doi/10.1021/acs.jpca.8b05901

187. Ultrafast Dynamics of the Metal to Ligand Charge Transfer Excited States of Ir(III) Proteo and Deutero Dihydrides. Taliaferro, C.M.; Danilov, E.O.; Castellano, F.N. J. Phys. Chem. A 2018, 122, 4430-4436.  https://pubs.acs.org/doi/10.1021/acs.jpca.8b02266

186. The Role of Excited State Vibrational Dynamics on Electronic Coherence in a Binuclear Pyrazolate Bridged Platinum(II) Phenylpyridine Complex. Radler, J.J.; Lingerfelt, D.B.; Castellano, F.N.; Chen, L.X.; Li, X. J. Phys. Chem. A 2018, 122, 5071-5077. https://pubs.acs.org/doi/10.1021/acs.jpca.8b01352

185. Coherent Vibrational Wavepacket Dynamics in Platinum(II) Dimers and Their Implications. Kim, P.; Kelley,M.S.J.; Chakraborty, A.; Schatz, G.C.; Castellano, F.N.; Chen, L.X.J. Phys. Chem. C 2018, 122, 14195-14204. (Kamat Festschrift) https://pubs.acs.org/doi/10.1021/acs.jpcc.8b01636

184. Positional Effects from σ-Bonded Platinum(II) on Intersystem Crossing Rates in Perylenediimide Complexes: Synthesis, Structures, and Photophysical Properties. Yarnell, J.E.; Davydenko,I.; Dorovatovskii,P.V.; Khrustalev, V.N.; Timofeeva, T.V.; Castellano, F.N.; Marder, S.R.; Risko, C.; Barlow, S. J. Phys. Chem. C 2018, 122, 13848-13862. (Kamat Festschrift) https://pubs.acs.org/doi/10.1021/acs.jpcc.8b01003

183. Nanocrystals for Triplet Sensitization – Molecular Behavior from Quantum Confined Materials. Garakyaraghi, S.; Castellano, F.N. Inorg. Chem. 2018, 57, 2351-2359. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03219

182. Enhancing the Visible Light Absorption and Excited State Properties of Cu(I) MLCT Excited States. Garakyaraghi, S.; McCusker, C.E.; Khan, S.; Koutnik, P.; Bui, A.T.; Castellano, F.N. Inorg. Chem. 2018, 57, 2296-2307. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03169

181. Diastereomerically-Differentiated Excited State Behavior in Ruthenium(II) Hexafluoroacetylacetonate Complexes of Diphenyl Thioindigo Diimine. Boice, G.N.; Garakyaraghi, S.; Patrick, B.O.; Sanz, C.A.; Castellano, F.N.; Hicks, R.G. Inorg. Chem. 2018, 57, 1386-1397. http://doi.org/10.1021/acs.inorgchem.7b02803

180. Cyclometalated Platinum(II) Charge Transfer Dimers Bridged by Hydroxypyridines. Chakraborty, A.; Yarnell, J.E.; Sommer, R.D.; Castellano, F.N. Inorg. Chem. 2018, 57, 1298-1310. http://doi.org/10.1021/acs.inorgchem.7b02736

179. Thermally Activated Delayed Photoluminescence from Pyrenyl Functionalized CdSe Quantum Dots. Mongin, C.; Moroz, P.; Zamkov, M.; Castellano, F.N. Nat. Chem. 2018, 10, 225-230. http://doi.org/10.1038/nchem.2906    

2017

178. Photochemical Upconversion in Water. El Roz, K.A.; Castellano, F.N. Chem. Commun. 2017, 53, 11705-11708.  http://doi.org/10.1039/c7cc07188d

177. Restricted Photoinduced Conformational Change in a Cu(I) Complex for Sensing Mechanical Properties. Razgoniaev, A.; McCusker, C.E.; Castellano, F.N.; Ostrowski, A. ACS Macro Letters 2017, 6, 920-924. http://pubs.acs.org/doi/abs/10.1021/acsmacrolett.7b00465

176. Efficient Phosphorescence from Naphthalenebenzimidizole Coordinated Iridium(III) Chromophores. Yarnell, J.E.; De La Torre, P.; Castellano, F.N. Eur. J. Inorg. Chem. 2017, 5238-5245.  DOI: 10.1002/ejic.201700669

175. Photoinduced Structural Distortions and Singlet-Triplet Intersystem Crossing in Cu(I) MLCT Excited States Monitored by Optically Gated Fluorescence Spectroscopy. Garakyaraghi, S.; Koutnik, P.; Castellano, F.N. Phys. Chem. Chem. Phys. 2017, 19, 16662-16668. https://doi.org/10.1039/c7cp03343e

174. Making Iron Glow. Castellano, F.N. Nature 2017, 543, 627-628. N&V Article. http://rdcu.be/qtff

173. Charge Localization after Ultrafast Photoexcitation of Rigid Perylene Perylenediimide Dyad Visualized by Transient Stark Effect. Koch, M.; Myahkostupov, M.; Oblinsky, D.G.; Wang, S.; Garakyaraghi, S.; Castellano, F.N.; Scholes, G.D. J. Am. Chem. Soc. 2017, 139, 5530–5537. https://doi.org/10.1021/jacs.7b01630

172. Can Excited State Electronic Coherence be Tuned via Molecular Structural Modification? A First-Principles Quantum Electronic Dynamics Study of Pyrazolate-Bridged Pt(II) Dimers. Lingerfelt, D.B.; Lestrange, P.J.; Radler, J.; Brown-Xu, S.E.; Kim, P.; Castellano, F.N.; Chen, L.X.; Li, X. J. Phys. Chem. A 2017, 121, 1932-1939. http://dx.doi.org/10.1021/acs.jpca.6b12099

171. Delayed Molecular Triplet Generation from Energized Lead Sulfide Quantum Dots. Garakyaraghi, S.; Mongin, C.; Granger, D.B.; Anthony, J.E.; Castellano, F.N. J. Phys. Chem. Lett. 2017, 8, 1458-1463. http://pubs.acs.org/doi/abs/10.1021/acs.jpclett.7b00546

170. Tuning Interfacial Spin Filters from Metallic to Resistive within a Single Organic Semiconductor Family. Wang, J.; Deloach, A.; Jiang, W.; Liu, F.; Papa, C.M.; Myahkostupov, M.; Castellano, F.N.; Dougherty, D.B. Phys. Rev. B 2017, 95, 241410-1-241410-5. https://doi.org/10.1103/PhysRevB.95.241410.

169. Effect of Polymer-Fullerene Interaction on the Dielectric Properties of the Blend. Constantinou, I.; Yi, X.; Shewmon, N.T.; Klump, E.D.; Peng, C.; Garakyaraghi, S.; Lo, C.K.; Reynolds,J.R.; Castellano, F.N.; So, F. Adv. Energy Mater. 2017, 1601947. http://dx.doi.org/10.1002/aenm.201601947

168. Efficient Generation of Long-lived Triplet Excitons in 2D Hybrid Perovskite. Younts, R.; Duan, H-S.; Gautam, B.; Saparov, B; Castellano, F.N.; Mitzi, D.; Gundogdu, K. Adv. Mater. 2017, 1604278. http://dx.doi.org/10.1002/adma.201604278

2016

167. Editorial for the ACS Select Virtual Issue on Emerging Investigators in Inorganic Photochemistry and Photophysics. Castellano, F.N. Inorg. Chem. 2016, 55, 12483-12487. 

166. Cuprous Phenanthroline MLCT Chromophore Featuring Synthetically Tailored Photophysics. Garakyaraghi, S.; Crapps, P.D.; McCusker, C.E.; Castellano, F.N. Inorg. Chem. 2016, 55, 10628-10636.

165. Liquid PEG Polymers Containing Antioxidants: A Versatile Platform for Studying Oxygen Sensitive Photochemical Processes. Mongin, C.; Golden, J.H.; Castellano, F.N. ACS Appl. Mater. Interfaces 2016, 8, 24038-24048. Issue Cover Sept. 2016.

164. Homogeneous Photocatalytic H2 Production using a Ru(II) Bathophenanthroline MLCT Photosensitizer. Khnayzer, R.S.; Olaiya, B.S.; El Roz, K.A.; Castellano, F.N. ChemPlusChem 2016, 81, 1090-1097. Issue Cover October 2016.

163. Enhanced Photophysics from Self-Assembled Cyclometalated Ir(III) Complexes in Water. McGoorty, M.M.; Khnayzer, R.S.; Castellano, F.N Chem. Commun. 2016, 52, 7846-7849.

162. 1-Pyrenyl and 3-Perylenyl Antimony(V) Derivatives for the Fluorescence Turn-on Sensing of Fluoride Ions in Water at sub-ppm Concentrations. Hirai, M.; Myahkostupov, M.; Castellano, F.N.; Gabbai, F.P. Organometallics 2016, 35, 1854-1860.

161. Butterfly Deformation Modes in a Photo-excited Pyrazolate-bridged Pt-complex Measured by Time-resolved X-ray Scattering in Solution. Haldrup, K.; Dohn, A. Shelby, M.L.; Mara, M.W.; Stickrath, A.B.; Harpham, M.R.; Huang, J.; Zhang, X.; Møller, K.B.; Chakraborty, A.; Castellano,F.N.; Tiede, D.M.; Chen, L.X. J. Phys. Chem. A 2016, 120, 7475-7483.

160. Materials Integrating Photochemical Upconversion. McCusker, C.E.; Castellano, F.N. Top. Curr. Chem. 2016, 374(2), 19.

159. Exposing the Excited State Equilibrium in an Ir(III) Bichromophore: A Combined Time Resolved Spectroscopy and Computational Study. Yarnell, J.E.; McCusker, C.E.; Leeds, A.J.; Breaux, J.M.; Castellano, F.N. Eur. J. Inorg. Chem. 2016, 1808-1818.

158. Direct Observation of Triplet Energy Transfer from Semiconductor Nanocrystals. Mongin, C.; Garakyaraghi, S.; Razgoniaeva, N.; Zamkov, M.; Castellano, F.N. Science 2016, 351, 369-372. 

157. Tunable Excited State Properties and Dynamics as a Function of Pt-Pt Distance in Pyrazolate-Bridged Pt(II) Dimers. Brown-Xu, S.; Kelley, M.; Fransted, K.; Chakraborty, A.; Schatz, G.; Castellano, F.N.; Chen, L.X. J. Phys. Chem. A 2016, 120, 543-550.

2015

156. MLCT Sensitizers in Photochemical Upconversion: Past, Present, and Potential Future Directions. Castellano, F.N.; McCusker, C.E. Dalton Trans. 2015, 44, 17906-17910.

155. Efficient Visible to Near-UV Photochemical Upconversion Sensitized by a Long Lifetime Cu(I) MLCT Complex. McCusker, C.E.; Castellano, F.N. Inorg. Chem.2015, 54, 6035-6042.

154. Bioinspired Design of Redox-Active Ligands for Multielectron Catalysis: Effects of Positioning Pyrazine Reservoirs on Cobalt for Electro- and Photocatalytic Generation of Hydrogen from Water. Jurss, J.W.; Khnayzer, R.S.; Panetier,J.A.; El Roz, K.A.; Head‐Gordon, M.; Long, J.R.; Castellano, F.N.; Chang, C.J. Chem. Sci. 2015, 6, 4954-4972.

153. Tetrahedral Rigid Core Antenna Chromophores bearing Bay-substituted Perylenediimides. Myahkostupov, M.; Castellano, F.N. Tetrahedron 2015, 71, 9519-9527.

152. Photochemical Upconversion and Annihilation Limit from a Boron Dipyrromethene Emitter. Deng, F.; Francis, A.J.; Weare, W.W.; Castellano, F.N. Photochem. Photobiol. Sci. 2015, 14, 1265-1270.

151. Near Infrared-to-Visible Photon Upconversion Enabled by Conjugated Porphyrinic Sensitizers under Low-Power Noncoherent Illumination. Olivier, J.-H.; Bai, Y.; Uh, H.; Yoo, H.; Therien, M.J.; Castellano, F.N. J. Phys. Chem. A 2015, 119, 5642-5649. 

150. Parallelization of Photocatalytic Gas-Producing Reactions. Khnayner, R.S.; Martin, D.; Codding, C.L.; Castellano, F.N. Rev. Sci. Instrum. 2015, 86, 034101-1-7.

149. Transient Absorption Dynamics of Sterically Congested Cu(I) MLCT Excited States. Garakyaraghi, S.; Danilov, E.O.; McCusker, C.E.; Castellano, F.N. J. Phys. Chem. A 2015, 119, 3181-3193.

148. Photon Upconversion Sensitized by a Ru(II)-Pyrenyl Chromophore. Deng, F.; Lazorski, M.; Castellano, F.N. Phil. Trans. R. Soc. A2015, 373, 20140322.

147. Enhancing Molecular Photophysics by Merging Organic and Inorganic Chromophores. Castellano, F.N. Acc. Chem. Res. 2015, 48, 828-839.

146. Sensing of TNT and 2,4-DNT in the Solid State with Photoluminescent Ru(II) and Ir(III) Complexes. Mosca, L.; Khnayzer, R.S.; Lazorski, M.S.; Danilov, E.O.; Castellano, F.N.; Anzenbacher Jr., P.A. Chem. Eur. J. 2015, 21, 4056-4064.

2014

145. Triplet State Formation in Homo- and Heterometallic Diketopyrrolopyrrole Chromophores. McCusker, C.E.; Hablot, D.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2014, 53, 12564-12571.

144. Photochemical Upconversion: The Primacy of Kinetics. Castellano, F.N.; Schmidt, T. J. Phys. Chem. Lett. 2014, 5, 4062-4072.

143. Excited State Equilibrium Induced Lifetime Extension in a Dinuclear Platinum(II) Complex. McCusker, C.E; Chakraborty, A.; Castellano, F.N. J. Phys. Chem. A 2014, 118, 10391-10399. (Current Topics in Photochemistry Issue)

142. Advances in the Light Conversion Properties of Cu(I)-based Photosensitizers. Lazorski, M.S.; Castellano, F.N. Polyhedron 2014, 82, 57-70.

141. Texaphyrin Sensitized NIR-to-Visible Photon Upconversion. Deng, F.; Sun. W.; Castellano, F.N. Photochem. Photobiol. Sci. 2014, 13, 813-819.

140. Intramolecular Radiationless Transitions Dominate Exciton Relaxation Dynamics. Jumper, C.C.; Anna, J.M.; Stradomska, A.; Schins, J.; Myahkostupov, M.;Prusakova, V.; Oblinsky, D.G.; Castellano, F.N.Knoester,J.; Scholes, G.D. Chem. Phys. Lett. 2014, 599, 23-33.

139. Light-Driven Hydrogen Evolution by BODIPY Sensitized Cobaloxime Catalysts. Bartelmess, J.; Francis, A.; El Roz, K.; Castellano, F.N.; Weare, W.W.; Sommer, R. Inorg. Chem. 2014, 53, 4527-4534.

138. Red-to-Blue/Cyan/Green Upconverting Microcapsules for Aqueous- and Dry-Phase Color Tuning and Magnetic Sorting. Kim, J.-H.; Deng, F.; Castellano, F.N.; Kim, J.-H. ACS Photonics 2014, 1, 382-388.   

137. Towards a Comprehensive Understanding of Visible-Light Photogeneration of Hydrogen from Water Using Cobalt(II) Polypyridyl Catalysts. Khnayzer,R.S.; Thoi, V.S.; Nippe, M.; King, A.E.; Jurss, J.W.; El Roz, K.A.; Long, J.R.; Chang, C.J.; Castellano, F.N. Energy Environ. Sci. 2014, 7, 1477-1488.

136. Robust Cuprous Phenanthroline Sensitizer for Solar Hydrogen Photocatalysis. Khnayzer, R.S.; McCusker, C.E.; Olaiya, B.S.; Castellano, F.N. J. Am. Chem. Soc. 2013, 135, 14068-14070.

135. Structural Refinement of Ladder-Type Perylenediimide Dimers: A Classical Tale of Conformational Dynamics. Myahkostupov, M.; Prusakova, V.; Oblinsky, D.G.; Scholes, G.D.; Castellano, F.N. J. Org. Chem. 2013, 78, 8634-8644.

134. Ultrafast Photoinduced Electron Transfer in Viologen-linked BODIPY Dyes. Frath, D.; Yarnell, J.E.; Ulrich, G.; Castellano, F.N.; Ziessel, R. ChemPhysChem, 2013, 14, 3348-3354.

133. Near-IR Phosphorescent Metalloporphyrin as a Photochemical Upconversion Sensitizer. Deng, F.; Sommer, J.R.; Myahkostupov, M.; Schanze, K.S.; Castellano, F.N. Chem Commun. 2013, 49, 7406-7408.

132. Design of a Long-Lifetime, Earth-Abundant, Aqueous Compatible Cu(I) Photosensitizer Using Cooperative Steric Effects. McCusker, C.E.; Castellano, F.N. Inorg. Chem. 2013, 52, 8114-8120.

131. Transition Metal Complexes of the Redox-Active Ligand bpy2py and their Evaluation for Catalytic Proton Reduction. Nippe, M.; Khnayzer, R.S.; Panetier, J.A.; Zee, D.Z.; Olaiya, B.S.; Head-Gordon, M.; Chang, C.J.; Castellano, F.N.; Long, J.R. Chem. Sci. 2013, 4, 3934-3945.

130. Tracking of Tuning Effects in Bis-Cyclometallated Iridium Complexes: A Combined TRIR, Electrochemical, and Computational Study. Chirdon, D.N.; McCusker, C.E.; Castellano, F.N.; Bernhard, S. Inorg. Chem. 2013, 52, 8795-8804.

129. Annihilation Limit of a Visible-to-UV Photon Upconversion Composition Ascertained from Transient Absorption Kinetics. Deng, F.; Blumhoff, J.; Castellano, F.N. J. Phys. Chem. A 2013, 117, 4412-4419.

128. Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Bridging Ligand. Donato, L.; McCusker, C.E.; Castellano, F.N.; Zysman-Colman, E. Inorg. Chem. 2013, 52, 8495-8504.

127.Towards Organic Photohydrides: Excited-state Behavior of 10-Methyl-9-phenyl-9,10-dihydroacridine. Yang, X.; Walpita, J.; Zhou, D.; Luk, H. L.; Vyas, S.; Khnayzer, R.; Subodh, T.; Diri, K.; Hadad, C.; Castellano, F.N.; Krylov, A.; Glusac, K. J. Phys. Chem. B 2013, 117, 15290-15296.(Fayer Festschrift)

126. Orange-to-Blue and Red-to-Green Photon Upconversion with a Broadband Absorbing Copper(I) MLCT Sensitizer. McCusker, C.E.; Castellano, F.N. Chem. Commun. 2013, 49, 3537-3539.  

125. Improving the Catalytic Activity of Semiconductor Nanocrystals through Selective Domain Etching. Khon, E.; Lambright, K.; Khnayzer, R.S.; Moroz, P.; Perera, D.; Butaeva, E.; Lambright, S.; Castellano, F.N.; Zamkov, M. Nano Lett. 2013, 13, 2016-2023.   

124. Diarylpyrenes vs. Diaryltetrahydropyrenes: Synthesis, Crystal Structures, Fluorescence, and Upconversion Photochemistry. El-Ballouli, A.O; Khnayzer, R.S.; Khalife, J.C. Fonari, A.; Hallal, K.M.; Timofeeva, T.V.; Patra, D.; Castellano, F.N.; Wex, B.; Kaafarani, B.R. J. Photochem. Photobiol. A: Chem. 2013, 272, 49-57.

123. Charge-Transfer and Ligand-Localized Photophysics in Luminescent Cyclometalated Pyrazolate-Bridged Dinuclear Platinum(II) Complexes. Chakraborty, A.; Deaton, J.C.; Haefele, A.; Castellano, F.N. Organometallics 2013, 32, 3819-3829.

122. Photochemical Upconversion: A Physical/Inorganic Chemistry Experiment for Undergraduates Using a Conventional Fluorimeter. Wilke, B.M.; Castellano, F.N. J. Chem. Ed. 2013, 90, 786-789.   

121. Ranking Solvent Interactions and Dielectric with [Pt(mesBIAN)(tda)]: A Cautionary Tale for Polarity Determinations in Ionic Liquid. Baker, G.A.; Rachford, A.A.; Castellano, F.N.; Baker, S.N. ChemPhysChem 2013, 14, 1025-1030.  

120. Stibonium Ions for the Fluorescence Turn-on Sensing of F in Drinking Water at ppm Concentrations. Ke, I.-S.; Myahkostupov, M.; Castellano, F.N.; Gabbai, F.P. J. Am. Chem. Soc. 2012, 134, 15309 – 15311.  

119. Structure and Activity of Photochemically Deposited “CoPi” Oxygen Evolving Catalyst on Titania. Khnayzer, R.S.; Mara, M.W.; Huang, J.; Shelby, M.L.; Chen, L.X.; Castellano, F.N. ACS Catal. 2012, 2, 2150-2160.

118. Photocatalytic Activity of Core/Shell Semiconductor Nanocrystals Featuring Spatial Separation of Charges.  Perera, D.; Lorek, R.; Khnayzer, R.S.; Moroz, P.; O’Connor, T.; Khon, D.; Diederich, G.; Kinder, E.; Castellano, F.N.; Zamkov, M. J. Phys. Chem. C 2012, 116, 22786-22793.

117. Metal Coordination Induced p-Extension and Triplet State Production in Diketopyrrolopyrrole Chromophores. McCusker, C.E.; Hablot, D.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2012, 51, 7957 – 7959.

116. Ligand Localized Triplet State Photophysics in a Platinum(II) Terpyridyl Perylenediimideacetylide.

      Prusakova, V.; McCusker, C.E.; Castellano, F.N. Inorg. Chem. 2012, 51, 8589 − 8598.

115. Dondorff Rings: Synthesis, Isolation, and Properties of 60º Bisterpyridine-based Folded Tetramers. Schultz, A.; Li, X.; McCusker, C.E.; Moorefield, C.N.; Castellano, F.N.; Wesdemiotis, C.; Newkome, G.R. Chem. Eur. J. 2012, 18, 11569 – 11572.

114. Spectroscopy and Photophysics in Cyclometalated Ru(II) Bis(Bipyridyl) Complexes. Muro-Small, M.L.; Yarnell, J.E.; McCusker, C.E.; Castellano, F.N. Eur. J. Inorg. Chem. 2012, 4004 – 4011.

113. Transition Metal Complexes Meet the Rylenes. Castellano, F.N. Dalton Trans. 2012, 41, 8493 – 8501. (Invited Perspective) Top 10 most downloaded articles in June 2012.

112. High Efficiency Low-Power Upconverting Soft Materials. Kim, J.-H.; Deng, F.; Castellano, F.N.; Kim, J.-H. Chem. Mater. 2012, 24, 2250-2252.

111. Getting to the (Square) Root of the Problem: How to Make Non-Coherent Pumped Upconversion Linear. Haefele, A.; Blumhoff, J.; Khnayzer, R.S.; Castellano, F.N. J. Phys. Chem. Lett. 2012, 3, 299-303. (Slideshare Presentation link: http://www.slideshare.net/jpcoffice/jpcl-jz300012u-castellano-presentation)  

110. Photocatalytic Hydrogen Production at Titania-Supported Pt Nanoclusters that are Derived from Surface-Anchored Molecular Precursors. Khnayzer, R.S.; Thompson, L.B.; Zamkov, M.; Ardo, S.; Meyer, G.J.; Murphy, C.J.; Castellano, F.N. J. Phys. Chem. C 2012, 116, 1429-1438.

109. Upconversion-Powered Photoelectrochemistry. Khnayzer, R.S.; Blumhoff, J.; Harrington, J.A.; Deng, F.; Haefele, A.; Castellano, F.N. Chem. Commun. 2012, 48, 209-211.

108. Charge Recombination to Oxidized Iodide in Dye Sensitized Solar Cells. Rowley, J.; Ardo, S.; Sun, Y.; Castellano, F.N.; Meyer, G.J. J. Phys. Chem. C 2011, 115, 20316-20325.

107.  Excited State Properties of Heteroleptic Ir(III) Complexes bearing Aromatic Hydrocarbons with Extended Cores. Spänig, F.; Olivier, J.-H.; Prusakova, V.; Retailleau, P.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2011, 50, 10859-10871.

106. Synthesis and Characterization of Tris(Heteroleptic) Ru(II) Complexes Bearing Styryl Subunits Myahkostupov, M.; Castellano, F.N. Inorg. Chem. 2011, 50, 9714-9727.  

105. Carbazole Donor and Carbazole or Bithiophene Bridged Sensitizers for Dye Sensitized Solar Cells. Onicha, A.C.; Panthi, K.; Kinstle, T.K.; Castellano, F.N. J. Photochem. Photobiol. A: Chem. 2011, 223, 57-64. 

104. Bidirectional “Ping-Pong” Energy Transfer and 3000-Fold Lifetime Enhancement in a Re(I) Charge Transfer Complex. Yarnell, J.E.; Deaton, J.C.; McCusker, C.E.; Castellano, F.N. Inorg. Chem. 2011, 50, 7820-7830. 

103. Phosphorescent Self-Assembled PtII Tetranuclear Metallocycles. Goeb, S.; Prusakova, V.; Wang, X.; Vézinat, A.; Sallé, M.; Castellano, F.N. Chem. Commun. 2011, 47, 4397 – 4399.

102. Coherence in Metal-Metal-to-Ligand-Charge-Transfer Transitions of a Dimetallic Complex Revealed by Ultrafast Transient Absorption Anisotropy. Cho, S.; Mara, M.W.; Wang, X.; Lockard, J.V.; Rachford, A.A.; Castellano, F.N.; Chen, L.X. J. Phys. Chem. A 2011, 115, 3990-3996. (Fleming Festschrift)

101. Dye-Sensitized Photovoltaic Properties of Hydrothermally Prepared TiO2 Nanotubes. Myahkostupov, M.; Zamkov, M.; Castellano, F.N. Energy Environ. Sci. 2011, 4, 998-1010.

100. Homogeneous Photocatalytic Hydrogen Production using p-Conjugated Pt(II) Arylacetylide Sensitizers. Wang, X.; Goeb, S.; Ji, Z.; Pogulyaychenko, N.; Castellano, F.N. Inorg. Chem. 2011, 50, 705-707.

99. Naphthalimide Phosphorescence Finally Exposed in a Platinum(II) Diimine Complex. Guo, H.; Muro-Small, M.L.; Ji,S.; Zhao, J.; Castellano, F.N. Inorg. Chem. 2010, 49, 6802-6804.

98. Triplet Excited State Distortions in a Pyrazolate Bridged Platinum Dimer Measured by X-ray Transient Absorption Spectroscopy. Lockard, J.V.; Rachford, A.A.; Smolentsev, G.; Strickrath, A.; Wang, X.; Zhang, X.; Atenkoffer, K.; Jennings, G.; Soldatov, A.; Rheingold, A.L.; Castellano, F.N.; Chen, L.X. J. Phys. Chem. A 2010, 114, 12780-12787. 

97. Supermolecular-Chromophore-Sensitized Near-Infrared-to-Visible Photon Upconversion. Singh-Rachford, T.N.; Nayak, A.; Goeb, S.; Muro-Small, M.L.; Therien, M.J.; Castellano, F.N. J. Am. Chem. Soc. 2010, 132, 14203-14211. 

96. Excited-State Electron Transfer from Ruthenium Polypyridyl Compounds to Anatase TiO2 Nanocrystallites: Evidence for a Stark Effect. Ardo, S.; Sun, Y.; Castellano, F.N.; Meyer, G.J. J. Phys. Chem. B 2010, 114, 14596-14604. (Wasielewski Festschrift)

95. Excited State Absorption Properties of Pt(II) Terpyridyl Complexes Bearing p-Conjugated Arylacetylides. Wang, X.; Goeb, S.; Ji, Z.; Castellano, F.N. J. Phys. Chem. B 2010, 114, 14440-14449. (Wasielewski Festschrift)

94. Viable Alternative to N-719 for Dye-Sensitized Solar Cells. Sun, Y.; Onicha, A.C.; Myahkostupov, M.; Castellano, F.N. ACS Appl. Mater. Interfaces 2010, 2, 2039-2045.

93. Platinum(II) Acetylide Photophysics. Muro, M.L.; Rachford, A.A.; Wang, X.; Castellano, F.N.  Top. Organomet. Chem. 2010, 29, 159-191.

92. Controlled Microwave Synthesis of RuII Synthons and Chromophores Relevant to Solar Energy Conversion. Sun, Y.; Machala, M.L.; Castellano, F.N. Inorg. Chim. Acta. 2010, 363, 283-287.

91. Low Power Photon Upconversion based on Sensitized Triplet-Triplet Annihilation. Singh-Rachford, T.N.; Castellano, F.N. Coord. Chem. Rev. 2010, 254, 2560-2573.

90. Triplet Sensitized Red-to-Blue Photon Upconversion. Singh-Rachford, T.N.; Castellano, F.N. J. Phys. Chem. Lett. 2010,1, 195-200.

89. Electrolyte-Dependent Photovoltaic Responses in Dye-Sensitized Solar Cells based on an Osmium(II) Complex of Mixed Denticity. Onicha, A.C.; Castellano, F.N. J. Phys. Chem. C 2010, 114, 6831-6840.

88. Boron Dipyrromethene (Bodipy) Phosphorescence Revealed in [Ir(ppy)2(bpy-C≡C-Bodipy)]+. Rachford, A.A.; Ziessel, R.; Bura, T.; Retailleau, P.; Castellano, F.N. Inorg. Chem. 2010, 49, 3730-3736.

87. Stark Effects after Excited-State Interfacial Electron Transfer at Sensitized TiO2 Nanocrystallites. Ardo, S.; Sun, Y.; Staniszewski, A.; Castellano, F.N.; Meyer, G.J. J. Am. Chem. Soc. 2010, 132, 6696-6709.  

86. Thermochromic Absorption and Photoluminescence in [Pt(ppy)(m-Ph2pz)]2. Rachford, A.A.; Castellano, F.N. Inorg. Chem. 2009, 48, 10865-10867. 

85. Influence of Temperature on Low-Power Upconversion in Rubbery Polymers. Singh-Rachford, T.N.; Lott, J.; Weder, C.; Castellano, F.N. J. Am. Chem. Soc. 2009, 131, 12007-12014.

84. Nonlinear Photochemistry Squared: Quartic Light-Power Dependence Realized in Photon Upconversion. Singh-Rachford, T.N.; Castellano, F.N. J. Phys. Chem. A 2009, 113, 9266-9269.

83. Photophysics in Platinum(II) Bipyridylacetylides. Muro, M.L.; Diring, S.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2009, 48, 11533-11542.

82. Solvent-induced Configuration Mixing and Triplet Excited State Inversion: Insights from Transient Absorption and Transient DC Photoconductivity Measurements. She, C.; Rachford, A.A.; Wang, X.; Goeb, S.; El-Ballouli, A.O.; Castellano, F.N.; Hupp, J.T. Phys. Chem. Chem. Phys. 2009, 11, 8586-8591.

81. Low Power Visible-to-UV Upconversion. Singh-Rachford, T.N.; Castellano, F.N. J. Phys. Chem. A 2009, 113, 5912-5917.

80. Supra-nanosecond Dynamics of a Red-to-Blue Photon Upconversion System. Singh-Rachford, T.N.; Castellano, F.N. Inorg. Chem. 2009,48, 2541-2548.           

79. [Pt(mesBIAN)(tda)]: A Near-Infrared Emitter and Singlet Oxygen Sensitizer. Rachford, A.A.; Hua, F.; Adams, C.J.; Castellano, F.N. Dalton Trans. 2009, 3950-3954.

78. Evolution of the Triplet Excited State in PtII Perylenediimides. Danilov, E.O.; Rachford, A.A. Goeb, S.; Castellano, F.N. J. Phys. Chem. A 2009, 113, 5763-5768.     

77. Boron Dipyrromethene Chromophores: Next Generation Triplet Acceptors/Annihilators for Low Power Upconversion Schemes. Singh-Rachford, T.N.; Haefele, A.; Ziessel, R.; Castellano, F.N. J. Am. Chem. Soc. 2008, 130, 16164-16165.

76. Microarray Pattern Recognition based on PtII Terpyridyl Chloride Complexes: Vapochromic and Vapoluminescent Response. Muro, M.L.; Daws, C.A.; Castellano, F.N. Chem. Commun. 2008, 6134-6136.

75. Slow Cation Transfer Follows Sensitizer Regeneration at Anatase TiO2 Interfaces. Staniszewski, A.; Ardo, S.; Sun, Y.; Castellano, F.N.; Meyer, G.J. J. Am. Chem. Soc. 2008, 130, 11586-11587.

74. Visible-Light Induced Water Detoxification Catalyzed by PtII Dye Sensitized Titania. Zhao, W.; Sun, Y.; Castellano, F.N. J. Am. Chem. Soc. 2008, 130, 12566-12567.

73. Ultrafast Excited State Dynamics in Pt(II) Chromophores Bearing Multiple IR Absorbers. Glik, E.A.; Kinayyigit, S.; Ronayne, K.; Towrie, M.; Sazanovich, I.V.; Weinstein, J.A.; Castellano, F.N. Inorg. Chem. 2008, 47, 6974-6983.     

72. Photophysics of the Platinum(II) Terpyridyl Terpyridylacetylide Platform and the Influence of Fe(II) and Zn(II) Coordination. Muro, M.L.; Diring, S.; Wang, X.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2008,47, 6796-6803.

71. Low-power Upconversion in Solid Polymer Films. Islangulov, R.R.; Singh, T.; Lott, J.; Weder, C; Castellano, F.N. Polymer Preprints 2008, 49, 1028-1029.

70. Accessing the Triplet Excited State in Perylenediimides. Rachford, A.A.; Goeb, S.; Castellano, F.N. J. Am. Chem. Soc. 2008, 130, 2766-2767.

69. Bi- and Terpyridyl Platinum(II) Chloro Complexes: Molecular Catalysts for the Photogeneration of Hydrogen from Water or Simply Precursors for Colloidal Platinum? Du, P.; Schnieder, J. Zhao, W.; Patel, U.; Castellano, F.N.; Eisenberg, R. J. Am. Chem. Soc. 2008,130, 5056-5058.   

68. Photochemical Upconversion Approach to Broad-Band Visible Light Generation. Singh-Rachford, T.N.; Islangulov, R.R.; Castellano, F.N. J. Phys. Chem. A 2008, 112, 3906-3910.

67. Ligand Localized Excited States in Platinum(II) Bipyridyl and Terpyridyl Peryleneacetylides. Rachford, A.A.; Goeb, S.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2008, 47, 4348-4355.

66. PdII Phthalocyanine-Sensitized Triplet-Triplet Annihilation from Rubrene. Singh-Rachford, T.N.; Castellano, F.N. J. Phys. Chem. A 2008, 112, 3550-3556.

65. Solvent-Induced Configuration Mixing and Triplet Excited State Inversion Exemplified in a Pt(II) Complex. Goeb, S.; Rachford, A.A.; Castellano, F.N. Chem. Commun. 2008,814-816. (Chemical Communications Cover Issue 7, 2008) 

64. Noncoherent Low-Power Upconversion in Solid Polymer Films. Islangulov, R.R.; Lott, J.; Weder, C.; Castellano, F.N. J. Am. Chem. Soc. 2007, 129, 12652-12653.

63. Room Temperature Luminescence from [Pt(4’-C≡CR-tpy)Cl]+ Complexes. Muro, M.L.; Castellano, F.N. Dalton Trans. 2007, 41, 4659 – 4665. (Dalton Transactions Cover November 7, 2007 Cover)

62. Luminescent Charge Transfer Platinum(II) Metallacycle. Hua, F.; Kinayyigit, S.; Rachford, A.A.; Shikhova, E.A.; Goeb, S.; Adams, C.J. Cable, J.R.; Kirschbaum, K.; Pinkerton, A.A.; Castellano, F.N. Inorg. Chem. 2007, 46, 8771-8783.

61. A Fulleropyrrolidine End-Capped Platinum-Acetylide Triad: The Mechanism of Photoinduced Charge Transfer in Organometallic Photovoltaic Cells. Guo, F.; Ogawa, K.; Kim, Y.-G.; Danilov, E.O.; Castellano, F.N.; Reynolds, J.R.; Schanze, K.S. Phys. Chem. Chem. Phys. 2007,9, 2724-2734. 

60. Excited State Absorption Properties of Platinum(II) Terpyridyl Acetylides. Shikhova, E.; Danilov, E.O.; Kinayyigit, S.; Pomestchenko, I.E.; Tregubov, A. D.; Camerel, F.; Retailleau, P.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2007, 46, 3038-3048.

59. Upconverted Emission from Pyrene and Di-tert-butylpyrene using Ir(ppy)3 as Triplet Sensitizer. Zhao, W.; Castellano, F.N. J. Phys. Chem. A 2006, 110, 11440-11445.

58. Photochemical Upconversion: Anthracene Dimerization Sensitized to Visible Light using Ru(II) Chromophores. Islangulov, R.R.; Castellano, F.N. Angew. Chem. Int. Ed. 2006, 45, 5957-5959; Angew. Chem. 2006, 118, 6103-6105.

57. Platinum(II) Diimine Diacetylides: Metallacyclization Enhances Photophysical Properties. Hua, F.; Kinayyigit, S.; Cable, J.R.; Castellano, F.N. Inorg. Chem. 2006, 45, 4304-4306. Inorganic Chemistry Cover May 29, 2006.Photophysical Processes in Bipyridyl and Terpyridyl Platinum(II) Acetylides. Castellano, F.N.; Pomestchenko, I.E.; Shikhova, E.; Hua, F.; Muro, M.L.; Rajapakese, N. Coord. Chem. Rev. 2006, 250, 1819-1828.

55. Photo Processes on Self-Associated Cationic Porphyrins and Plastocyanin Complexes 1. Ligation of Plastocyanin Tyrosine 83 onto Metalloporphyrin and Electron Transfer Fluorescence Quenching. Anula, H.M.; Myshkin, E.; Guliaev, A.; Luman, C.R.; Danilov, E.O.; Castellano, F.N.; Bullerjahn, G.S.; Rodgers, M.A.J. J. Phys. Chem. A 2006, 110, 2545-2559.

54. Direct Interrogation of Triplet Intraligand Excited States using Nanosecond Step-Scan FT-IR. Polyansky, D.; Danilov, E. O.; Castellano, F.N. Inorg. Chem. 2006, 45, 2370-2372.

53. Low Power Upconversion Using MLCT Sensitizers. Islangulov, R.R.; Kozlov, D.V.; Castellano, F.N. Chem. Commun.2005, 3776-3778. (Issue 30 Inside Cover & Featured as Hot Article; C&EN News of the Week Aug. 8, 2005)

52. Influence of a Gold(I)-Acetylide Bond on the Photophysics of Re(phen)(CO)3Cl. Pomestchenko, I.E.; Polyansky, D.; Castellano, F.N. Inorg. Chem. 2005, 44, 3412-3421.             

51. Ultrafast Energy Migration in Platinum(II) Diimine Complexes Bearing Pyrenylacetylide Chromophores. Danilov, E.O.; Pomestchenko, I.E.; Kinayyigit, S.; Gentili, P.L.; Hissler, M.; Ziessel, R.; Castellano, F.N. J. Phys. Chem. A 2005, 109, 2465-2471.

50. Green Photoluminescence from Platinum(II) Complexes Bearing Silylacetylide Ligands. Hua, F.; Kinayyigit, S.; Cable, J.R.; Castellano, F.N. Inorg. Chem. 2005, 44, 471-473.

49. Photochemically Reversible Luminescence Lifetime Switching in Metal-Organic Systems. Kozlov, D.V.; Castellano, F.N. J. Phys. Chem. A 2004, 108, 10619-10622.

48. Anti-Stokes Delayed Fluorescence from Metal-Organic Bichromophores. Kozlov, D.V.; Castellano, F.N. Chem. Commun. 2004, 2860-2861.

47. Room Temperature Phosphorescence from Ruthenium(II) Complexes Bearing Conjugated Pyrenylethynylene Subunits. Kozlov, D.V.; Tyson, D.S.; Goze, C.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2004, 43, 6083-6092.

46. Near-Field Optical Addressing of Luminescent Photoswitchable Supramolecular Systems Embedded in Inert Polymer Matrices. Ferri, V.; Scoponi, M.; Bignozzi, C.A.; Tyson, D.S.; Castellano, F.N.; Doyle, H.; Redmond, G. Nano Lett. 2004, 4, 835-839.

45. Solvent Switching Between Charge Transfer and Intraligand Excited States in a Multichromophoric Platinum(II) Complex.  Pomestchenko, I.E.; Castellano, F.N. J. Phys. Chem. A 2004, 108, 3485-3492.

44. Bipyridine and Terpyridine Based Ruthenium Metallosynthons for Grafting of Multiple Pyrene Auxiliaries. Goze, C.; Kozlov, D.V.; Castellano, F.N.; Suffert, J.; Ziessel, R. Tetrahedron Lett. 2003, 44, 8713-8716.

43. Synthesis and Photophysics of Ruthenium(II) Complexes with Multiple Pyrenylethynylene Subunits. Goze, C.; Kozlov, D.V.; Tyson, D.S.; Ziessel, R.; Castellano, F.N. New J. Chem. 2003, 27, 1679-1683.

42. Directed Assembly of Chiral Organometallic Squares that Exhibit Dual Luminescence. Lee, S.J.; Luman, C.R.; Castellano, F.N.; Lin, W. Chem. Commun. 2003, 2124-2125.

41. Dinuclear Metal-Organic Material for Binary Optical Recording. Trouts, T.D.; Tyson, D.S.; Pohl, R.; Kozlov, D.V.; Waldron, A.G.; Castellano, F.N. Adv. Funct. Mater. 2003, 13, 398-402.

40. Lengthening of Fluorescence Lifetimes in Self-Organized Metal-Organic Assemblies. Luman, C.R.; Castellano, F.N. Photochem. Photobiol. 2003, 77, 510-514.

39. Room Temperature Phosphorescence from a Platinum(II) Diimine Bis(pyrenylacetylide) Complex. Pomestchenko, I.E.;  Luman, C.R.; Hissler, M.; Ziessel, R.; Castellano, F.N. Inorg. Chem. 2003, 42, 1394-1396.

38. Photodriven Electron and Energy Transfer from a Light-Harvesting Metallodendrimer. Tyson, D.S.; Luman, C.R.; Castellano, F.N. Inorg. Chem. 2002, 41, 3578-3586.

37. Luminescence Lifetime-Based Sensor for Cyanide and Related Anions. Anzenbacher Jr., P.; Tyson, D.S.; Jursíková, K.; Castellano, F.N. J. Am. Chem. Soc. 2002, 124, 6232-6233.

36. Metal-Organic Approach to Binary Optical Memory. Tyson, D.S.; Bignozzi, C.A.; Castellano, F.N., J. Am. Chem. Soc. 2002, 124, 4562-4563.

35. Excited State Processes in Ruthenium(II)/Pyrenyl Complexes Displaying Extended Lifetimes. Tyson, D.S.; Henbest, K.B.; Bialecki, J.; Castellano, F.N. J. Phys. Chem. A, 2001, 105, 8154-8161.

34. New Ru(II) Chromophores with Extended Excited State Lifetimes. Tyson, D.S.; Luman, C.R.; Zhou, X.; Castellano, F.N. Inorg. Chem. 2001, 40, 4063-4071.

33. First Generation Light-Harvesting Dendrimers with a [Ru(bpy)3]2+ Core and Aryl Ether Ligands Functionalized with Coumarin 450. Zhou, X.; Tyson, D.S.; Castellano, F.N. Angew. Chem. Int. Ed. 2000, 39, 4301-4305; Angew. Chem. 2000, 112, 4471-4475.

32. Ruthenium(II) Complex with a Notably Long Excited State Lifetime. Tyson, D.S.; Bialecki, J.; Castellano, F.N. Chem. Commun. 2000, 2355-2356.

31. Long Range Resonance Energy Transfer to [Ru(bpy)3]2+. Tyson, D.S.; Gryczynski, I.; Castellano, F.N. J. Phys. Chem. A 2000, 104, 2919-2924.

30. Intramolecular Singlet and Triplet Energy Transfer in a Ru(II) Diimine Complex Containing Multiple Pyrenyl Chromophores. Tyson, D.S.; Castellano, F.N. J. Phys. Chem. A 1999, 103, 10955-10960.

29. Light-Harvesting Arrays with Coumarin Donors and MLCT Acceptors. Tyson, D.S.; Castellano, F.N. Inorg. Chem. 1999, 38, 4382-4383.

28. Long-Lifetime Lipid Rhenium Metal-Ligand Complex for Probing Membrane Hydrodynamics. Li, L.; Castellano, F.N.; Gryczynski, I.; Lakowicz, J.R. Chem. & Phys. of Lipids. 1999,99(1), 1-9.

27. Glucose Sensor for Low Cost Lifetime-Based Sensing Using a Genetically Engineered Protein. Tolosa, L.; Gryczynski, I.; Eichhorn, L.; Dattelbaum, J.D.; Castellano, F.N.; Rao, G.; Lakowicz, J.R. Anal. Biochem. 1999, 267, 114-120.

26. Two-Photon Excitation of Rhenium Metal-Ligand Complexes.  Lakowicz, J.R.; Castellano, F.N.; Gryczynski, I.; Gryczynski, Z.; Dattelbaum, J.D. J. Photochem. and Photobiol. A: Chemistry 1999, 122, 95-101.

25. Advances in Fluorescence Spectroscopy: Multi-Photon Excitation, Engineered Proteins, Modulation Sensing, and Microsecond Rhenium Metal-Ligand Complexes. Lakowicz, J.R.; Gryczynski, I.; Tolosa, L.; Dattelbaum, J.D.; Castellano, F.N.; Li, L.; Rao, G. Acta Phys. Pol. A 1999, 95, 179-196.

24. Low Frequency Modulation Sensors Using Nanosecond Fluorophores.  Lakowicz, J.R.; Castellano, F.N.; Dattelbaum, J.D.; Tolosa, L.; Rao, G.; Gryczynski, I. Anal. Chem. 1998, 70, 5115-5121.

23. A Long-Lifetime Ru(II) Metal-Ligand Complex as a Membrane Probe. Guo, X.Q.; Castellano, F.N.; Li, L.; Lakowicz, J.R. Biophys. Chem. 1998, 71, 51-62.

22. A Long-Lived, Highly Luminescent Rhenium (I) Metal-Ligand Complex as a Probe of Biomolecules. Castellano, F.N.; Guo, X.Q.; Li, L.; Szmacinski, H.; Sipior, J.; Lakowicz, J.R. Proc. SPIE, 1998, 3256, 223-233.

21. Long Lifetime Ru(II) Complexes for the Measurement of High Molecular Weight Protein Hydrodynamics. Szmacinski, H.; Castellano, F.N.; Terpetschnig, E.; Dattelbaum, J.D.; Lakowicz, J.R.; Meyer, G.J. Biochim. Biophys. Acta 1998, 1383, 151-159.

20. Electron and Energy Transfer From Cu(I) MLCT Excited States. Ruthkosky, M.; Kelly, C.A.; Castellano, F.N.; Meyer, G.J. Coord. Chem. Rev. 1998, 171, 309-322.

19. Use of a Long-Lifetime Re(I) Complex in Fluorescence Polarization Immunoassays of High Molecular Weight Analytes. Guo, X.Q.; Castellano, F.N.; Li, L.; Lakowicz, J. R. Anal. Chem. 1998, 70, 632-637.

18. Water Soluble Luminescence Oxygen Sensor. Castellano, F.N.; Lakowicz, J.R. Photochem. Photobiol. 1998, 67, 179-183.

17. Long-Lifetime Ru(II) Complexes as Labeling Reagents for Sulfhydryl Groups. Castellano, F.N.; Dattelbaum, J.D.; Lakowicz, J.R. Anal. Biochem. 1998, 255, 165-170.

16. Light-Induced Processes in Molecular Gel Materials. Castellano, F.N.; Meyer, G.J. Prog. Inorg. Chem. 1997, 44, 167-208.

15. A Long-Lived Highly Luminescent Rhenium(I) Metal-Ligand Complex as a Biomolecular Probe. Guo, X.Q.; Castellano, F.N.; Li, L.; Lakowicz, J.R.; Sipior, J. Anal. Biochem. 1997, 254, 179-186.

14. Two-Photon Excitation of Ethidium Bromide Labeled DNA. Malak, H.; Castellano, F.N.; Gryczynski, I.; Lakowicz, J.R. Biophys. Chem. 1997, 67, 35-41.

13. Light Induced Charge Separation at Sensitized Sol-Gel Processes Semiconductors. Stipkala, J.M.; Castellano, F.N.; Heimer, T.A.; Kelly, C.A.; Livi, K.J.T.; Meyer, G.J. Chem. Mater. 1997, 9, 2341-2353.

12. Creation of Metal-to-Ligand Charge Transfer Excited States with Two-Photon Excitation. Castellano, F.N.; Malak, H.; Gryczynski, I.; Lakowicz, J.R. Inorg. Chem. 1997, 36, 5548-5551.

11. Long-Lifetime Metal-Ligand Complexes as Luminescent Probes for DNA. Malak, H.; Gryczynski, I.; Lakowicz, J.R.; Meyer, G.J.; Castellano, F.N. J. Fluorescence 1997, 7, 107-112.

10. Light Induced Charge Separation Across Ru(II)-Modified Nanocrystalline TiO2 Interfaces With Phenothiazine Donors. Argazzi, R.; Bignozzi, C.A.; Heimer, T.A.; Castellano, F.N.; Meyer, G.J. J. Phys. Chem. B 1997, 101, 2591-2597.

9. Photodriven Electron and Energy Transfer from Copper Phenanthroline Excited States. Ruthkosky, M.; Castellano, F.N.; Meyer, G.J. Inorg. Chem. 1996, 35, 6406-6412.

8. Long-Lived Photoinduced Charge Separation across Nanocrystalline TiO2 Interfaces. Argazzi, R.; Bignozzi, C.A.; Heimer, T.A.; Castellano, F.N.; Meyer, G.J. J. Am. Chem. Soc. 1995, 117, 11815-11816.

7. DNA Dynamics Observed With Long-Lifetime Metal-Ligand Complexes. Lakowicz, J.R.; Malak, H.; Gryczynski, I.; Castellano, F.N.; Meyer, G.J. Biospectroscopy 1995, 1, 163-167.

6. Photodriven Energy Transfer From Cuprous Phenanthroline Derivatives. Castellano, F.N.; Ruthkosky, M.; Meyer, G.J. Inorg. Chem. 1995, 34, 3-4.

5. Dynamic Electron Transfer in Aquo- and Alco- SiO2 Gels. Castellano, F.N.; Meyer, G.J. J. Phys. Chem. 1995, 99, 14742-14748.

4. Enhanced Spectral Sensitivity from Ruthenium(II) Polypyridyl Based Photovoltaic Devices. Argazzi, R.; Bignozzi, C.A.; Heimer, T.A.; Castellano, F.N.; Meyer, G.J. Inorg. Chem. 1994, 33, 5741-5749.

3. Spectroscopic and Excited-State Properties of Titanium Dioxide Gels. Castellano, F.N.; Stipkala, J.M.; Friedman, L.A.; Meyer, G.J. Chem. Mater. 1994, 6, 2123-2129.

2. Photophysical Properties of Ruthenium Polypyridyl Photonic SiO2 Gels. Castellano, F.N.; Heimer, T.A.; Tandhasetti, M.T.; Meyer, G.J. Chem. Mater. 1994, 6, 1041-1048.

1. Hydroxyl Radical Production in the Reactions of Copper-Containing Amine Oxidases with Substrates. Castellano, F.N.; He, Z.; Greenaway, F.T. Biochim. Biophys. Acta 1993, 1157, 162-166.